The reaction of l-triphenylsilyl-2-propenyllithium with ethylene oxide afforded an adduct, a lithium salt of 3-triphenylsilyl-4-penten-I-ol, which regenerated an allyllithium species, 3-1ithio-5triphenylsiloxy-l-pentene via anionic rearrangement ofa silyl group from carbon to oxide in the presence o
A carbon-carbon bond formation using endoperoxides of 1,2-dihydropyridines
✍ Scribed by Mitsutaka Natsume; Yasuo Sekine; Masashi Ogawa; Hiroe Soyagimi; Yoshinori Kitagawa
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 246 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
A novel type of a nucleophilic substitution on the piperidine ring was achieved by a stannous chloride-effected reaction of endoperoxides of N-
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