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A C 78 Fullerene Precursor: Toward the Direct Synthesis of Higher Fullerenes

✍ Scribed by Amsharov, Konstantin Yu.; Jansen, Martin

Book ID: 120215198
Publisher: American Chemical Society
Year: 2008
Tongue: English
Weight: 90 KB
Volume: 73
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo7027008

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## Abstract Multicyclic cagelike cyclophanes 2 a and 2 b containing cyclobutene rings have been prepared as precursors of three‐dimensional polyynes C~78~H~18~ (1 a) and C~78~H~12~Cl~6~ (1 b), respectively. Laser irradiation of 2 a and 2 b induced expulsion of the aromatic fragment, indane, to give