✦ LIBER ✦

A broadband ADEQUATE pulse sequence using chirp pulses

✍ Scribed by Matthias Köck; Rainer Kerssebaum; Wolfgang Bermel

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 143 KB
Volume: 41
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1097

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✦ Synopsis

Abstract

Recently, we have introduced the ADEQUATE pulse sequence as a sensitive method to observe ^13^C,^13^C correlations in natural products. This kind of experiment suffers from offset‐dependent effects of the 180°(^13^C) pulses. Here we describe an application of smoothed chirp pulses in the ADEQUATE pulse sequence which allows ^13^C,^13^C correlations to be run without any offset dependences. This experiment is called chirp ADEQUATE and was applied to δ‐valerolactone and cholesteryl acetate. This modification will allow a general application of the ADEQUATE pulse sequence. Copyright © 2002 John Wiley & Sons, Ltd.

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