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A Bis(phosphinimino)methanide Lanthanum Amide as Catalyst for the Hydroamination/Cyclization, Hydrosilylation and Sequential Hydroamination/Hydrosilylation Catalysis.

✍ Scribed by Marcus Rastaetter; Agustino Zulys; Peter W. Roesky


Publisher
John Wiley and Sons
Year
2006
Weight
29 KB
Volume
37
Category
Article
ISSN
0931-7597

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Bis(phosphinimino)methanide Rare Earth A
✍ Marcus RastΓ€tter; Agustino Zulys; Peterβ€…W. Roesky πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 309 KB πŸ‘ 2 views

## Abstract A series of yttrium and lanthanide amido complexes [Ln{N(SiHMe~2~)~2~}~2~{CH(PPh~2~NSiMe~3~)~2~}] (Ln=Y, La, Sm, Ho, Lu) were synthesized by three different pathways. The title compounds can be obtained either from [Ln{N(SiHMe~2~)~2~}~3~(thf)~2~] and [CH~2~(PPh~2~NSiMe~3~)~2~] or from K