Bis(phosphinimino)methanide Rare Earth A
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Marcus RastΓ€tter; Agustino Zulys; Peterβ
W. Roesky
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Article
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2007
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John Wiley and Sons
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English
β 309 KB
π 2 views
## Abstract A series of yttrium and lanthanide amido complexes [Ln{N(SiHMe~2~)~2~}~2~{CH(PPh~2~NSiMe~3~)~2~}] (Ln=Y, La, Sm, Ho, Lu) were synthesized by three different pathways. The title compounds can be obtained either from [Ln{N(SiHMe~2~)~2~}~3~(thf)~2~] and [CH~2~(PPh~2~NSiMe~3~)~2~] or from K