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A biomimetic route to the ergot derailment products, the clavicipitic acids - detection of a reactive intermediate by 31p nmr - some chemical underpinnings for a proposed intermediate in ergot alkaloid biosynthesis.

✍ Scribed by Alan P. Kozikowski; Makoto Okita


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
252 KB
Volume
26
Category
Article
ISSN
0040-4039

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✦ Synopsis


A biomimetic route to the clavicipitic acids has been developed which is based on the Mitsunobu reaction of the diol 4a.