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A biomimetic approach to the Elaeocarpus alkaloids. Syntheses of (.+-.)-elaeokanine A, (.+-.)-elaeokanine C, (.+-.)-elaeocarpidine, and (.+-.)-tarennine

โœ Scribed by Gribble, Gordon W.; Switzer, Frank L.; Soll, Richard M.

Book ID
121308361
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
932 KB
Volume
53
Category
Article
ISSN
0022-3263

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Elaeocarpus Alkaloids. The Synthesis of
Elaeocarpus Alkaloids. The Synthesis of dl-Elaeokanine-A and dl-Elaeokanine-C.
โœ Joseph J. Tufariello; Sk.Asrof Ali ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 199 KB

The synthesis of dl-elaeokanine-A and dl-elaeokanine-C is described by an approach which utilizes a nitrone cycloaddition to generate a B-aminoketone, which upon annulation produces one or the other of the title alkaloids depending upon conditions. We wish to describe herein a synthetic entry into t