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A biogenetically patterned first total synthesis of (±)-6-epijunicedranol (or junicedran-11-ol)

✍ Scribed by A Srikrishna; P.Praveen Kumar

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 129 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00216-5

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✦ Synopsis

The first total synthesis of (±)-6-epijunicedranol (4), employing a biogenetically patterned earbonium ion mediated cyclisafion and rearrangement of an enone for the efficient generation of four contiguous quaternary carbon atoms, is described.

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