๐”– Bobbio Scriptorium
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A bicyclo[2.1.0]pentane phenonium ion

โœ Scribed by H.W. Whitlock Jr.; Phil Fuchs Jr.


Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
161 KB
Volume
9
Category
Article
ISSN
0040-4039

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Rate of acetolysis of bicyclo[2.1.0]Pent
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Free radical chlorination of bicyclo[2.1
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Reaction of chlorine with bicyclo[2.l.Olpentane in chloroform at -2pC has been reported to occur by electrophilic addition to the three membered ring leading to a 1,3-chloronium ion and to give predominantly dichlorides (1). Free radical chlorinations of several strained bicyolic systems (2) have be

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The oxidation of bicyclo[2.1.0]pentane by isolated dimethyldioxirane and by the more powerful methyl(trifluoromethyl)dioxirane, affords selectively, the corresponding endo-2 alcohol along with the 2,3-diol in high yield, and no rearrangement products; this suggests that a concerted O-insertion mecha