A bicyclo[2.1.0]pentane phenonium ion
โ Scribed by H.W. Whitlock Jr.; Phil Fuchs Jr.
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 161 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
Reaction of chlorine with bicyclo[2.l.Olpentane in chloroform at -2pC has been reported to occur by electrophilic addition to the three membered ring leading to a 1,3-chloronium ion and to give predominantly dichlorides (1). Free radical chlorinations of several strained bicyolic systems (2) have be
The oxidation of bicyclo[2.1.0]pentane by isolated dimethyldioxirane and by the more powerful methyl(trifluoromethyl)dioxirane, affords selectively, the corresponding endo-2 alcohol along with the 2,3-diol in high yield, and no rearrangement products; this suggests that a concerted O-insertion mecha