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A basic ionic liquid catalyzed reaction of benzothiazole, aldehydes, and 5,5-dimethyl-1,3-cyclohexanedione: Efficient synthesis of tetrahydrobenzo[b]pyrans

✍ Scribed by Li-Rong Wen; Huai-Yuan Xie; Ming Li


Publisher
Journal of Heterocyclic Chemistry
Year
2009
Tongue
English
Weight
148 KB
Volume
46
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

magnified image

A fast, mild, and quantitative procedure for the preparation of tetrahydrobenzo[b]pyran derivatives in the presence of an easily accessible basic ionic liquid—[bmIm]OH(3‐butyl‐1‐methylimidazoliumhydroxide) as the catalyst has been developed. The ionic liquid was stable during the reaction process and could also be reused at least nine times with consistent activity. This procedure may be a practical alternative to the existing procedures to meet the need of academe as well as industries. J. Heterocyclic Chem., (2009).


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