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A B3LYP/6-31G(d) study of Diels-Alder reactions between cyclopentadiene and (E)-2-arylnitroethenes

✍ Scribed by Jasiński, Radomir ;Koifman, Oskar ;Barański, Andrzej

Book ID
111488272
Publisher
Walter de Gruyter GmbH
Year
2011
Tongue
English
Weight
891 KB
Volume
9
Category
Article
ISSN
2391-5420

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The mechanism of the sodium amide initiated amination of pyridine, known as the Chichibabin reaction, was investigated at the B3LYP/6-31+G(d) level of theory. Although this reaction has been known for more than one hundred years, it remains a very useful and sometimes unique method for the synthesis