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A B3LYP and QTAIM study of a new proton donor for dihydrogen bonds: the case of the C2H5+···nBeH2complexes (n

✍ Scribed by B. G. Oliveira; M. L. A. A. Vasconcellos

Publisher
Springer
Year
2009
Tongue
English
Weight
355 KB
Volume
20
Category
Article
ISSN
1040-0400

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The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th