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A 3,7-Diaza-l,2,4,5,6,8-hexaphosphatricyclo-[4.2.0.02,5]octane, a [2 + 2] Dimer of a 1,2-Dihydro-l-azatriphosphete containing a Planar P4 Substructure

✍ Scribed by Prof. Dr. Edgar Niecke; Oliver Altmeyer; Martin Nieger; Dr. Fritz Knoll


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
241 KB
Volume
26
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES


Dodecamethyl-1Ξ»3,4Ξ»3-diphospha-2,3,5,6,7
✍ Prof. Dr. Martin DrΓ€ger; Dr. Bernd Mathiasch πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 233 KB

**White phosphorus reacts with 1,1,2,2‐tetramethyldislannane in the dark at 0Β°C to give the title compound**, which according to an X‐ray structure analysis has D~3~‐symmetry. The bicyclo[2.2.2]octane framework with P in the bridgehead position is constructed from three Sn~4~P~2~ six‐membered rings