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A 3 Tt 5 Phases Sr 3 Sn 5 , Ba 3 Pb 5 , and La 3 Sn 5 . Structure and Bonding in a Series of Isotypic Metallic Compounds with Increased Electron Count and Their Comparison with the Nominal Zintl Phase La 3 In 5

✍ Scribed by Klem, Michael T.; Vaughey, J. T.; Harp, Jason G.; Corbett, John D.


Book ID
126042171
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
218 KB
Volume
40
Category
Article
ISSN
0020-1669

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I4/mcm, No. 140) and of Ba 5 Si 3 F 0.16 (P4/ncc, Ba 5 Si 3 -type) were re5ned from single-crystal X-ray di4raction data. The interstitial H, F atoms are bound in a constricted tetrahedral (A 2 Ψ‰ ) 4 cavity in the Cr 5 B 3 -type heavy atom structure, which can be described ideally as (A 2 Ψ‰ ) 5 (Tt