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A 2,2‘-Biphosphinine Dianion: Synthesis and Reactivity

✍ Scribed by Rosa, Patrick; Ricard, Louis; Mathey, François; Le Floch, Pascal

Book ID
126023374
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
96 KB
Volume
18
Category
Article
ISSN
0276-7333

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✍ Hervé Lesnard; Thibault Cantat; Pascal Le Floch; Isabelle Demachy; Yves Jean 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 502 KB

## Abstract The geometric and electronic structure of formally d^6^ tris‐biphosphinine [M(bp)~3~]^__q__^ and tris‐bipyridine [M(bpy)~3~]^__q__^ complexes were studied by means of DFT calculations with the B3LYP functional. In agreement with the available experimental data, Group 4 dianionic [M(bp)~

Ruthenium(II) complexes of a 2,2′-biphos
Ruthenium(II) complexes of a 2,2′-biphosphinine
✍ Duncan Carmichael; Pascal Le Floch; Louis Ricard; François Mathey 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 532 KB

The biphosphinine complexes [RuCl,(dmso),(bp)] (2) and cis-[Reclad] (3) (bp = 4,4',5,5'-tetramethyl-2,2'biphosphinine) have been prepared from [RuCl,(dmso),,] and the free ligand. The crystal and molecular structure of 2, which crystallised in the space group C2/c with a = 17.329(l), b = 16.008(l),