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A 19F NMR study of the asymmetric short hydrogen bond in the crystalline adduct between potassium fluoride and succinic acid

✍ Scribed by E.A. Moore; M. Mortimer; N.F. Peirson; G. Oates

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 337 KB
Volume: 151
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)85276-x

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✦ Synopsis

An NMR method for investigating strong hydrogen bonding in solids is demonstrated for the adduct, KF.(CH2C02H)2.

A procedure for analysmg the 19F NMR FID for KF.(CH2C02H), is described and the results for the geometry of the 0-H...F... H-O hydrogen-bonded system are compared with those of the X-ray structure. The value of the H...F bond length is found to be 0.148 k 0.003 nm which is significantly shorter than that determined by X-ray analysis.

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