The 13C NMR spectra of a series of derivatives of carbazole and azacarbazole (norharmane or 9H-pyrido[3,4-b]indole) are reported. The dependence of 'H and 'T shieldings on molecular geometry is discussed briefly. KEY WORDS'~C NMR Dimeric 8-carbolines Azacarbazoles 9H-Pyrido[3,4-b]indoles Carbazole d
A 13C NMR study of β-carboline alkaloids
✍ Scribed by Kazuo Koike; Yohko Sakamoto; Taichi Ohmoto
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 228 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
✦ Synopsis
The 13C NMR spectra of p-carboline alkaloids were determined, and unambiguous assignments of the spectra were carried out from the long-range coupling constants.
📜 SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract The first total synthesis of the β‐carboline alkaloids arenarine A **(1)** and arenarine B **(2)** is described. Methanolysis of the α‐bromoketone **9** gives **1** in good yield. Alternatively **1** can be obtained from the diazoketone **11** with boron trifluoride/methanol in poor yie
C and in some cases also 15 N chemical shifts of quaternary benzo[c]phenanthridine alkaloids (fagaronine, chelerythrine, chelilutine, chelirubine, nitidine, sanguilutine, sanguinarine, and sanguirubine) were systematically studied by NMR spectroscopy and ab initio calculations. The assignment of sig