2-(4-Hydroxyalkyl)-1,3-dioxolanes (3a/3b, 5-7) undergo an via the benzylic carbenium ion B and the 1,3-dioxolan-2ylium cation C, is supported by the stereochemistry of the acid-catalyzed rearrangement to give 2-hydroxyethyl alkanoic esters 8-11. The postulated mechanism, proceeding reaction and the
β¦ LIBER β¦
A 1,3-hydride shift in the rearrangement of (1-phenylallyl)oxyacetic acid to 2-ethyl-2-phenyl-1,3-dioxolan-4-one
β Scribed by Eberle, Marcel K.; Kahle, Gerard G.
- Book ID
- 126961666
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 681 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0002-7863
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