## Abstract Given the nucleophilicity of the {Pt~2~S~2~} ring, the evolution of [Pt~2~(μ‐S)~2~(P∩P)~2~] (P∩P=1,2‐bis(diphenylphosphino)ethane (dppe), 1,3‐bis(diphenylphosphino)propane (dppp)) metalloligands in the presence of the simplest electrophilic species, the proton, has been studied. Combine
A 117Sn and 31P NMR study of trans-[Pt(SnCl3)nCl2−n(P(CH2CH3)3)2] (n = 1,2) in acetone: the effect of solvent
✍ Scribed by K.R. Koch; G.V. Fazakerly; E. Dijksta
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 90 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0020-1693
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✦ Synopsis
The complexes in question exhibit very interesting catalytic properties in the reactions of decomposition of organic hydroperoxides and olefm epoxidation.
Further investigations on the preparation of this type of complexes with molybdenum in other oxidation states in aqueous solutions are in progress.
📜 SIMILAR VOLUMES
I9'Pt-, 31Pand "N-NMR. data are presented for [PtCl, (t-Bu15N=CH-CH=15N (t-Bu)) (q2-styrene)] (l), truns-[(PtC12 (PBu3)}, (~-BU'~N=CH-C'H=I~N (2-Bu))] (2), trans-[PtCI, (~-Bu"N=CH-CH='~N (t-Bu)) (PBu,)] (3) and various complexes of the type truns-[PtCl, (N-ligand) (PBu,)]. In solution the gross stru