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96/05958 Fullerene formation in acetylene/oxygen/argon/chlorine flames

Publisher: Elsevier Science
Year: 1996
Weight: 192 KB
Volume: 37
Category: Article
ISSN: 0140-6701
DOI: 10.1016/s0140-6701(97)83369-3

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✦ Synopsis

04 By-products related to fuels 96105948 Effect of gra t hite of FeCI,-graphltr lntercalatlon 96/05959 Fullereno production drlven by long.pulses of compounds on the meaop aae development In coal tar pitch near-Infrared laser radlatlon

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The impact of Cl, addition on the fullerene formation in acetylene/oxygen/argon flat flames burning at low pressure was investigated. The quantities of C,, and CT0 in the soot were determined by HPLC after extraction with toluene. Negative ion mass spectra were measured using chemical ionization by

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Amounts between 2.5 and 5.9% of HBr, HCl and CIZ were added to fullerene forming benzene/oxygen/argon flat-flames burning at 75 mbar in an attempt to affect halogen substitutions in the carbon framework. The inhibition effect of HBr dramatically reduced the yield of fullerene, while it stayed in the