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96/05547 The high-temperature pyrolysis of hexachloropropene: Kinetic analysis of pathways to formation of perchloro-arylbenzenes


Book ID
103520606
Publisher
Elsevier Science
Year
1996
Weight
186 KB
Volume
37
Category
Article
ISSN
0140-6701

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The high-temperature pyrolysis of hexach
โœ Philip H. Taylor; Debra A. Tirey; Barry Dellinger ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 806 KB

We present the results of a study of the thermal degradation of hexachloropropene in a tubular flow reactor with in-line GC-MS product analysis. Hexachloropropene was observed to be thermally fragile with initial reaction products (T < 773 K) including CCI 4, C2C14, C2C16, and C3C14, (a). At higher