9,10-Phenanthrenocyaninatoeisen(II) (PhcFe) und axial koordinierte Isocyanid-Komplexe
✍ Scribed by Hanack, Michael ;Renz, Günter
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1990
- Tongue
- English
- Weight
- 646 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0009-2940
No coin nor oath required. For personal study only.
✦ Synopsis
Isocyanide complexes / Porphyrin derivatives / Semiconductors, organic 9,1&Phenanthrenocyaninatoiron(II) (PhcFe) and Axially Coordinated Isocyanide Complexes 9,10-Phenanthrenocyaninatoiron(II) (PhcFe) is synthesized inatoiron(I1) (PcFe). Isocyanides RNC (R = tBu, cHx, Bzl, from 9,lO-dicyanophenanthrene (3) and pentacarbonyliron. Me,Ph) react with PhcFe to form the corresponding bisaxially PhcFe exhibits similar spectroscopic properties (UV/VIS and substituted 9,10-phenanthrenocyaninatoiron(II) compounds MoBbauer spectra) and similar oxidation potentials as 42-4 -7. Reaction of PhcFe with 1,4-diisocyanobenzene (dib) Naphthalocyaninatoiron(I1) (1.2-NcFe) and Phthalocyan-yields the bridged complex [PhcFe(dib)],.