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9-Thiabicyclo[4.2.1]nona-2,4,7-triene 9,9-dioxide

โœ Scribed by Gasteiger, Johann; Huisgen, Rolf


Book ID
127146246
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
321 KB
Volume
94
Category
Article
ISSN
0002-7863

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The synthesis of l,l-dimethyl-l-silacyclopent-5-enes from the alkali metal induced 1,4-addition of dimethyldichlorosilane to 1,5-dienes' has been dramatically extended by Dunogues, Calas and coworkers2 through the use of magnesium as the metal and hexamethylphosphoramide (HMPA) as the solvent. This