Phenyl-and 8,9-diphenylbicyclo[5.2.O]nonatetraenyl anion, obtained in fairly stable solutions by base treatment of the corre-Toyonaka, Osaka 560, Japan sponding bicyclo[5.2.0]nona-1,3,5,8-tetraenes, display properties characteristic of aromatic systems. Recently we have reported the synthesis and X-
9-phenylbicyclo[6.1.0]nonatetraenyl anion: A new diatropic 10 π-electron system
✍ Scribed by Takeshi Kawase; Masaji Oda
- Book ID
- 104220928
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 146 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Swmary : Treatment of 9-chloro-9-phenylbicyclo[6.l.O]nona-2,4,6-triene with excess bases gives, by the intermediacy f 9-phenylbicyclor6.1.01-1(9),2,4,6_tetraene, 9-phenylbicycloC6.1.O]tetraenyl anion of which 9 H-NMR spectrum suggests some diatropic character of the molecule.
📜 SIMILAR VOLUMES
The (alpha =3, beta =2) member of the (A3ABO6) (A3B3O9) homologous series has been stabilised in the Sr-Rh-O system for a [Sr10(Sr0.5Rh1.5)TP(Rh6)Oh]O24 composition. The structural characterisation has been performed by powder X-ray and electron diffraction measurements and high-resolution electron