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9-Naphthylmethylenecyclooctatrienyl anions. Conformational analysis and bond rotation

โœ Scribed by Staley, Stuart W.; Dustman, Charles K.; Linkowski, Gerard E.


Book ID
126446846
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
629 KB
Volume
103
Category
Article
ISSN
0002-7863

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Conformation and rotational barriers of
โœ G. Boche; K. Buckl; D. Martens; D.R. Schneider ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 259 KB

The conformati ons and the rotational barriers of the 2-substituted 1,3-diphenylallylanions lb-g (Tab.2) have been determined. Increasing size of the substituents leads tomore exo,endo-and endo,endo-conformers at the cost of the exo,exo-species. This trend is connected with decreasing AG\*-values of