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9-{2-[Bis(pivaloyloxymeth­oxy)phosphinylmeth­oxy]eth­yl}adenine dihydrate

✍ Scribed by Chang, Ying ;Zheng, Qi-Tai ;Lu, Yang


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
198 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, C 20 H 32 N 5 O 8 PÁ2H 2 O, molecules are linked to each other via intermolecular N-HÁ Á ÁO, N-HÁ Á ÁN, O-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds with the water molecules acting as both acceptors and donors.


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Dipotassium salt of a double-armed terep
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Single crystals of the the title compound, 2K^+^·C~58~H~56~O~18~ ^2−^·4CH~3~OH, were obtained from a methanol solution. The anion is centrosymmetric; consequently the asymmetric unit contains one-half of the salt and two methanol molecules. Each polyether chain contains one K^+^, which is coordinate

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The title compound, C 20 H 22 N 8 O 2 S 2 , contains a center of inversion at the mid-point of the central C-C bond. The mean planes of the phenyl and the 1H-tetrazol-5-ylsulfanyl rings make a dihedral angle of 53.95 (16) .

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The title salt, C~8~H~20~NO~5~ ^+^·C~7~H~4~NO~4~ ^−^·H~2~O, is composed of a 4-nitrobenzoate anion, a [2-hydroxy-1,1-bis(hydroxymethyl)ethyl]bis(2-hydroxyethyl)ammonium (NBHHP) cation and a water molecule. The three units are linked by O—H...O hydrogen bonds.