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8-oxoheptafulvene. II The reaction with benzophenone and tropones

โœ Scribed by Noboru Morita; Yoshio Kitahara; Toyonobu Asao


Book ID
108383334
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
173 KB
Volume
13
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


8-oxoheptafulvene VI. Further reactions
โœ Noboru Morita; Toyonobu Asao; Yoshio Kitahara ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 209 KB

We have reported that the reaction of 8-oxoheptafulvene with tropone and its derivatives afforded several products including (2 + 8)cycloadducts with cycloheptatriene and norcaradiene moieties, heptafulvalenes, and 1-oxaazulan-2-ones with cyclohexa-1,4-diene moiety at 3 and 4-positions, and we have

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## Recently we reported the formation of 8-oxoheptafulvene (I) and its reaction with olefins and carbonyl compounds including benzophenone, tropones and benzotroponesto give various adducts which were mainly resulted from a chemical property of ketene moiety of I.

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