7Li NMR and DSC investigations of lithium phospholipid interactions
✍ Scribed by J.F.M. Post; D.A. Wilkinson
- Book ID
- 107788230
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 418 KB
- Volume
- 143
- Category
- Article
- ISSN
- 0021-9797
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## Abstract ^7^Li and ^13^C solid‐state MAS NMR spectra of three lithium cuprates with known X‐ray structures—lithium([12]crown‐4)~2~ dimethyl and diphenyl cuprate (1,2) and lithium(thf)~4~‐[tris(trimethylsilyl) methyl]~2~ cuprate (3)—have been measured and analysed with respect to the quadrupolar
Lithium-7 quadrupolar coupling constants, s(7Li), were measured for a number of microcrystalline lithium amides by solid-state 7Li magic angle spinning (MAS) NMR. A linear correlation between s(7Li) and the structural NÈLiÈN angle known from x-ray di †raction work was found : s(7Li) \ (4.1 ^0.5) ‡ N