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7Li Double Quantum Filtered NMR and Multinuclear Relaxation Rates of Clay Suspensions: The Effect of Clay Concentration and Nonionic Surfactants

✍ Scribed by J. Grandjean; J.-L. Robert


Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
64 KB
Volume
138
Category
Article
ISSN
1090-7807

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✦ Synopsis


Li double quantum NMR spectra were used to investigate ordering process of synthetic Li ؉ -saponites dispersed in water. Synthetic clays suspended in aqueous solutions of poly(ethylene glycol) monoalkyl ethers were also studied by 7 Li, 23 Na, and 13 C NMR techniques. The strongest surfactant-Li ؉ -saponite interaction occurs with the lowest charged clay. Laponite interacts more strongly with organic molecules than does a similarly charged saponite. The number of oxyethylene units rather than the chain length seems to govern the solid-surfactant interaction.