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79Br and 81Br isotope effects in Raman spectra of crystalline NaBrO3

✍ Scribed by J.B. Bates; H.D. Stidham


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
187 KB
Volume
16
Category
Article
ISSN
0038-1098

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Long-range 37Cl/35Cl and 81Br/79Br isoto
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NMR studies of the 13C isotope shift between and and of the linewidths of the two resolved CH 3 79Br CH 3 81Br resonances were carried out as part of a wider study of the NMR properties of methyl halide molecules. The isotope shift of 1.12 ppb can be readily accounted for in terms of the very slight

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## Abstract Splittings in the ^13^C cross‐polarization magic angle spinning spectra of 1, 4‐dibromobenzene and 4‐bromo‐3, 5‐dimethylpyrazole are reported. They arise from (^79,81^Br, ^13^C) interactions influenced by the quadrupolar nature of the bromine nuclei. They are analysed using both ‘invers