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7,10,14-Tri-t-butyl-3-amino-1,8-bisdehydro[14]annulene

✍ Scribed by Takeshi Satake; Yasunobu Onishi; Masahiko Iyoda; Masazumi Nakagawa

Publisher: Elsevier Science
Year: 1979
Tongue: French
Weight: 143 KB
Volume: 20
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)95352-3

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✦ Synopsis

Sumnary: Tri-t-butylcarboxybisdehydro[lrl]annulene was converted by the Curtius reactiog into unstable aminoannulene, which could be characterized as N-acetyl derivative. The pKa-value of the aminoannulene reflects aromatic nature of the annulene nucleus. Aminoannulenes are interesting compounds being formal counterpart of aniline. However, little is known hitherto on amino derivative of annulene!'2) Because we have previously prepared 7,10,14-tri-t-butyl-3-carboxy-1,8-bisdehydro[14]annulene

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