70 eV electron impact mass spectra of substituted pyrrolizidin-2-one derivatives
β Scribed by Paul F. Keusenkothen; Michael B. Smith
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 251 KB
- Volume
- 319
- Category
- Article
- ISSN
- 0022-2860
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## Abstract The electron impact mass spectra of the 3,5βbis(trifluoromethyl)benzeneboronate, 2,4βdichlorobenzeneβboronate and 4βbromobenzeneboronate derivatives of some bifunctional diols and aminoalcohols are characterized by prominent molecular ions with diagnostically useful modes of fragmentati
Fragmentation pathways of the title compounds under electron impact were compared to those of their (1aryl)substituted analogs reported earlier. The main fragmentation route of the M Γ ions is the sulphamide N-S bond cleavage leading to [M Γ ArSO 2 ] ions. No loss of the alkyl substituents from the
Table 1. The EI mass spectra, showing peaks of >5% relative abundance (RA), of compounds 1-10, using 70 eV electrons Compound m/z (% RA) 1 315(M, 55) 314(10) 161(10) 160(89) 159(13) 107(12) 106(100) 105(11) 104(9) 91(33) 77(22) 65(15) a 2 345(M, 4) 316(7) 315(19) 314(100) 190(11) 175(7) 172(5) 160(1