Several groups of workers have in recent years attempted to synthesize a 2,3-diaxabicycle [2.2.1] heptyl ring system with a keto function at the 'I-position. All such attempts have failed. The reason for this was that the synthetic sequence involved preparation of
7-Monooxygenated 2,3-diazabicyclo[2.2.1]heptanes
✍ Scribed by J.J. Tufariello; J.J. Spadaro Jr.
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 170 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The ^13^C n.m.r. spectra of 11 derivatives of 2,3‐dimethylenenorbornane, 1–11, of 5 derivatives of 2,3‐dimethylene‐7‐oxanorbornane, 12–16, and of 2,3,5,6‐tetramethylene‐7‐oxanorbornane (17) have been measured and the chemical shifts have been assigned. The effects of 1‐methyl, 5‐hydroxy
The title compound, C 19 H 28 N 2 O 3 , was obtained by the acidic hydrolysis of (1S,4R)-1-isocyanato-7,7-dimethylbicyclo[2.2.1]heptan-2-one followed by addition of aqueous sodium hydroxide. N-HÁ Á ÁO hydrogen bonds link the molecules into chains running along the a axis.