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6Li and 15N Nuclear Magnetic Resonance Studies of Mixed Alkali Metal Cation Hexamethyldisilazide Bases

✍ Scribed by Nichols, Michael A.; Waldmueller, Delia; Williard, Paul G.


Book ID
126267899
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
256 KB
Volume
116
Category
Article
ISSN
0002-7863

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## Abstract The base‐catalyzed ο£ΏNH~2~ exchange reactions of acetamide and thioacetamide were studied by ^15^N nuclear magnetic resonance spectroscopy by the use of line‐shape analysis. The ^15^N NMR spectra of these primary amides at intermediate exchange rates were broad doublets, which indicated