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6Li, 6Li-cosy - a new tool for structure determinations of lithium organic compounds in solution

✍ Scribed by Harald Günther; Detlef Moskau; Ralf Dujardin; Adalbert Maercker

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
174 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

A homonuclear sLi,eLi shift correlation experiment has been successfully performed for 3,4-dilithio-2,5-dimethyl-2,4-hexadiene, thereby providing information about the structure of this compound.

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✍ Bernd Böhler; Harald Günther 📂 Article 📅 1996 🏛 Elsevier Science 🌐 French ⚖ 114 KB

A 2D-HMQC experiment has been performed for the first time to correlate 6Li and 29Si resonances using scalar 6Li,29Si coupling in dilithium 1,4-diyl-l,4-diphenyl-l.2,3.4-tetrakis(trimethylsilyl)butane, where 2j(6Li.29Si) and 3j(6Li,29Si) amount to 0.3 and 0.7 Hz, respectively.