6,9-Dimethoxy-2,13-diaza[4]paracyclo[4](3,5)-pyridinophane-1,14-dione, C19H21N3O4, and 19-benzyl-16,19-dihydro-2,13-diaza[4]paracyclo[4](3,5)pyridinophane-1,14-dione, C24H25N3O2
β Scribed by van Herk, A. M. ;Goubitz, K. ;Overbeek, A. R. ;Stam, C. H.
- Book ID
- 114528197
- Publisher
- International Union of Crystallography
- Year
- 1982
- Weight
- 415 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0567-7408
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
In the title compound, C~18~H~20~N~4~O~3~, a glycoluril derivative, the oxadiazinane six-membered ring displays a chair conformation and the bridgehead cyclohexane ring a boat conformation. In the crystal structure, intermolecular CβH...O hydrogen bonds may help to establish the packing.
## Abstract The molecular structures of the title compounds 3 and 5 were investigated by NMR and Xβray structural methods. The NMR results suggest two equivalent halves for both molecules. The Xβray study shows an approximate mirror plane for 3 and an approximate twofold axis for a significant port