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[6+4] Cycloaddition reactions of acceptor thiophene dioxides: The synthesis of substituted azulenes

✍ Scribed by A. M. Moiseev; E. S. Balenkova; V. G. Nenajdenko


Publisher
Springer
Year
2006
Tongue
English
Weight
424 KB
Volume
55
Category
Article
ISSN
1573-9171

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## Abstract 1‐(Bromoacetyl)‐3‐methylazulene **(1a)** and methyl 3‐(bromoacetyl)azulene‐1‐carboxylate **(1b)** reacted with thioamides **3a,b** and thioureas **3c,d** in boiling ethanol to give the corresponding (4‐thiazolyl)azulenes **4a‐d** and **5a‐d** in good yields, respectively. The reactions