𝔖 Bobbio Scriptorium
✦   LIBER   ✦

63Cu and 31P endor study of Tetra-n-Butylammonium-(Maleonitriledithiolato) (Monoethyldithiophosphato) cuprate(II)/Nickelate(II) (n-Bu4N)[Cu/Ni(mnt)(H(et)dtp)]

✍ Scribed by R. Kirmse; R. Bröttcher; C.P. Keijzers


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
461 KB
Volume
87
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis


The 63Cu quadrupole the 63Cu hypcrfine and .

3tP hypcrfiic couphng tensors of the mued-lqand chelrlc (n-Bu4N)[63Cu(mnt)(H(et)dtp)]

doped into the corresponding nickel comples hzve been measured by ENDOR spectroscopy. Conclusions rue drzwn concerntng the symmetry of the Cu complex. The 63Cu quadrupolc tensor and the HP hyperline tensor can be understood assummg B "tnnnnnulu Cu 3d+,z-P 3s overlap".