638. Alkylperoxy-radicals. Part I. Reactions with 2: 4: 6-trialkylphenols
โ Scribed by Bickel, A. F. ;Kooyman, E. C.
- Book ID
- 121236063
- Publisher
- The Royal Society of Chemistry
- Year
- 1953
- Weight
- 817 KB
- Category
- Article
- ISSN
- 0368-1769
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๐ SIMILAR VOLUMES
A photoinitiation technique has been used to study the gas-phase reactions of specific alkylperoxy radicals derived from azomethane and 2,3-dimethylbutane. The rate of production of radicals is controlled and measured at temperatures (~100ยฐC), where the number of reactions is reduced so as to permit
i-C4HgON0 was photolyzed with 366-nm radiation at -8, 23, 55, 88, and 120ยฐC in a static system in the presence of NO, O,, and N2. The quantum yield of i-C,H7CH0, @{i-C3H7CHO}, was measured as a function of reaction conditions. The primary photochemical act is and it proceeds with a quantum yield &