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6. The dithiole series. Part II. Reactions of 1,2- and 1,3-dithiolium salts with nucleophilic reagents

✍ Scribed by Leaver, D. ;McKinnon, D. M. ;Robertson, W. A. H.


Book ID
120268850
Publisher
The Royal Society of Chemistry
Year
1965
Weight
866 KB
Category
Article
ISSN
0368-1769

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Reactions of 3,5-Diaryl-1,2-dithiolium S
✍ Hartke, Klaus ;Kraska, Andreas ;Massa, Werner ;Molinier, Michel ;Wocadlo, Sigrid πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 913 KB

## Abstract Reaction of the 3,5‐diaryl‐1,2‐dithiolium salts 2 with the metal cyclopentadienides 4 and 9 leads to the formation of the tricyclic compounds 6 and 10 via a ring‐opened intermediate, which undergoes an intramolecular Diels‐Alder cyclization. Compounds 6 and 10 rearrange by treatment wit