6-Nitro-1-deazapurine
✍ Scribed by Müller, Jens ;Gil Bardají, Elisa ;Polonius, Fabian-Alexander
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 214 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The title compound, C 6 H 4 N 4 O 2 , is a potential nucleobase surrogate. In the crystal structure, molecules are linked by intermolecular N-HÁ Á ÁN hydrogen bonds [HÁ Á ÁN = 1.88 (3) A ˚] to form one-dimensional chains in the b-axis direction.
📜 SIMILAR VOLUMES
## Abstract The synthesis of 6‐substituted 1‐deazapurine 2′‐deoxyribonucleosides is described. Glycosylation of the 1‐deazapurine (imidazo[4,5‐__b__]pyridine) anions with the α‐D‐halogenose 5 gives stereoselectively __N__^7^‐ and __N__^9^‐ regioisomers. ^1^H‐NMR NOE and ^13^C‐NMR spectroscopy are u
In the title compound, C 14 H 10 N 2 O 4 S, the nitro group, confirmed as being in the 6-position, is coplanar with the indole ring system and the angle between the planes of the indole system and the phenyl ring is 96.1 (1) .