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6-Deoxy-allo-nojirimycin in the racemic and d-series, 6-deoxy-d,l-talo-nojirimycin, their 1-deoxyderivatives and 6-deoxy-2-d,l-allosamine via hetero-Diels-Alder cycloadditions

✍ Scribed by Albert Defoin; Hervé Sarazin; Jacques Streith

Book ID
108378749
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
836 KB
Volume
53
Category
Article
ISSN
0040-4020

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✍ Albert Defoin; Hervé Sarazin; Jacques Streith 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 871 KB

Nucleophilic ring opening of the cyclic sulfates (+)-9c and D-9c and of the epoxide (+)-13, or double substitution of the bis-triflate D-10 (derived from the Diels-Alder aAhwt of h~ldicnal dime~ylac~tai to aehiral or enantiometieally pure nitroso-derivatives) led to ~xynojirimycin and 6-deoxy-gu/o..