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6-alkoxy-3,4-dihydro-2h-pyrans from substituted α,β-unsaturated esters

✍ Scribed by H.K. Hall Jr.; H.A.A. Rasoul; M. Gillard; M. Abdelkader; P. Nogues; R.C. Sentman


Book ID
104220401
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
212 KB
Volume
23
Category
Article
ISSN
0040-4039

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2-Ethoxy-3,4-dihydro-2H-pyran-6-carbonitriles are obtained in high yield by stereospecific endo-mode cycloadditions of ccJ-unsaturated acyl cyanides and ethyl vinyl cther at room temperature. The nitrile group is converted to some other functionalities.