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5H-[1]Benzoselenino[2,3-b]pyridine—A Novel Heterocyclic Ring System

✍ Scribed by Dipl.-Chem. Behrouze Pakzad; Prof. Dr. Klaus Praefcke; Dr. Helmut Simon


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
211 KB
Volume
16
Category
Article
ISSN
0044-8249

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✦ Synopsis


In continuation of our work on photo-and electron collision-induced reactions of thi01-l~~ and selenol-esters", 61 we have now synthesized the selenocarboxylic Se-aryl esters (2)-( 5 ) as first examples exhibiting liquid crystal properties. The positions of their carbonyl absorptions are typical for this class of compound^"^. R' R2 Yield M.p.


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## A simple route to the synthesis of the pharmaceutically important thieno[2,3-d]pyrimidine derivatives and of thieno[2,3-b]pyridine derivatives via the use of 5-amin0-3-phenylthiophene-2,Cdicarbonitrile (2) as a starting material is described.