591. Mechanism of the azide–nitrite reaction. Part II
✍ Scribed by Stedman, G.
- Book ID
- 121224948
- Publisher
- The Royal Society of Chemistry
- Year
- 1959
- Weight
- 544 KB
- Volume
- 0
- Category
- Article
- ISSN
- 0368-1769
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📜 SIMILAR VOLUMES
## The kinetics of the reaction between permanganate and nitrite in acid medium were studied spectrophotometrically by the stopped flow method. The observed rate equation was v = k,[HN02] + kzk3 [HNOJ' [Mn( VII)] k3 [Mn(VII)] + k_zK [H+J [HNOa] In perchloric acid medium at 25 + 0.1 "C, with an ion
## Abstract Results on the oxidation of N by Br~2~ in neutral and acid media are presented. The rate of the reaction is found to be proportional to [N] and [Br~2~]. The gaseous product of oxidation is found to be pure nitrogen. The stoichiometry of the reaction is The reaction shows a positive sa