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57Fe hyperfine interactions in the magnetic phase of fayalite, Fe2SiO4

✍ Scribed by S.S. Hafner; J. Stanek; M. Stanek


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
634 KB
Volume
51
Category
Article
ISSN
0022-3697

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The spin-coupling model of the {[Fe4S4]-siroheme} center of the active site of sulfite reductase is developed. The tetmmer-siroheme coupling 2JthS j -s h results in the induced paramagnetism of individual ions of the Fe/S tetramer which = ~ \_\_ 33/j .j. provides non-zero effective hyperfine consta