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57Fe and 119Sn Mössbauer studies of electron exchange processes in spinels of composition Zn2+[Zn(1−x)22+Sn(1+x)24+Fe(1−x2+]O4

✍ Scribed by M.J. Tricker; P.P. Vaishnava; J.F. Marshall; J.D. Donaldson; R.M.A. Grimsey


Book ID
115976658
Publisher
Elsevier Science
Year
1981
Weight
381 KB
Volume
43
Category
Article
ISSN
0022-1902

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Members of the solid solution series Znl\_xF%A1204 (x = 0.2, 0.4, 0.6 and 1.0) with spinel structure were synthesized by direct solid-state reaction of the simple metal oxides and metallic iron in evacuated silica ampoules at 1175 ~ C. Two aliquots of the single-phase spinels obtained for each compo