5,7-Dibromo-N-tosylquinolin-8-amine
✍ Scribed by Silva, Luiz Everson da ;Joussef, Antonio Carlos ;Foro, Sabine ;Schmidt, Boris
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 313 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Zn(C 17 H 7 Br 2 F 6 N 2 O 2 S) 2 ], the zinc(II) ion has a distorted tetrahedral geometry formed by the N atoms of the quinoline and the sulfonamide groups. One intermolecular C-HÁ Á ÁO hydrogen bond to a sulfonyl O atom is observed.
On the basis of X-ray diffraction data and quantum-chemical calculations the role of medium polarity and intramolecular interactions (including N••• and NO 2 ••• ) in the stabilization of the conformers of N-(5,7-dinitro-8-quinolinyl)-N-(4-nitrophenyl)amine has been demonstrated.