Repetitive Diels-Alder reactions' of 1,2,5,6-tetra-exo-methylenecyclooctane (3) and [2.2]-(2,3)-furanophane (6) provide novel band-type atructurea. 3 and 6 differ significantly in the relative rate of the first and second cycloaddition. Redox polymers with separate electrophores (= electroactive gro
✦ LIBER ✦
5,6,7,8-Tetramethylenebicyclo[2.2.2]oct-2-ene as “Bis(diene)” in Repetitive Diels-Alder Reactions
✍ Scribed by Wegener, Stefan ;Müllen, Klaus
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1991
- Tongue
- English
- Weight
- 324 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0009-2940
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## Abstract The kinetics of the thermal reactions of bicyclo[4.2.2]deca‐3,7‐diene (BDD) and endo‐ and exo‐5‐vinylbicyclo[2.2.2]oct‐2‐ene (endo‐ and exo‐VBO) have been studied in the gas phase. The temperature range was 459–526 K for BDD, 476–563 K for endo‐VBO, and 513–578 K for exo‐VBO. The initia