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55Mn, 13C coupling constants of some σ- and π-organomanganese complexes

✍ Scribed by Vladimir Torocheshnikov; Daniel Rentsch; Wolfgang von Philipsborn

Book ID
102527833
Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
439 KB
Volume
32
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

^55^Mn, ^13^C coupling constants of σ‐ and π‐organomanganese pentacarbonyl, tetracarbonylphosphine and tricarbonyl complexes were determined by lineshape analysis of the ^13^CO and ^13^C(R) signals (R = alkyl, acyl or aryl) using the iterative lineshape fitting program QUADR. The ^1^J(^55^Mn, ^13^C) data are in the range 29–47 Hz for MnCO bonds and 2–28 Hz for MnR bonds. The ^55^Mn chemical shifts and linewidths are also reported.

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