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5,5′-Bi-5H-cyclopenta[2,1-b;3,4-b′]dipridinylidene, a New Bridging Ligand for Metal Complexes. Preliminary Communication

✍ Scribed by Marianne Riklin; Alex von Zelewsky

Book ID
102256317
Publisher
John Wiley and Sons
Year
1996
Tongue
German
Weight
221 KB
Volume
79
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

5,5′‐Bi‐5__H__‐cyclopenta[2,1‐b;3,4‐b′]dipyridinylidene(1) was synthesized in three steps from 9,10‐phenanthroline and characterized by UV/VIS and NMR spectroscopy, mass spectrometry, and cyclic voltammetry. Its ability to act as a bridging ligand is demonstrated by the synthesis of the complexes Ru(bpy)~2~(1)~2~ (6) and {Ru(bpy)~2~}~2~(1)~4~ (7) (bpy = 2,2′‐bipyridine).

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